A dinuclear Rh(−<scp>i</scp>)/Rh(<scp>i</scp>) complex bridged by biphilic phosphinine ligands

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چکیده

A dinuclear Rh(− i )/Rh( ) complex bridged by tridentate phosphinine ligands was prepared reduction of the corresponding Rh( complex. An unsymmetric bridging mode differentiated electronic environments Rh centres.

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2023

ISSN: ['2041-6520', '2041-6539']

DOI: https://doi.org/10.1039/d3sc02292g